축전식 탈염공정을 이용한 하수중의 용존염 제거특성 연구 (The removal characteristics of dissolved solid in wastewater during a capacitive deionization process)

서지정보

· 발행기관 : 대한상하수도학회
· 수록지 정보 : 상하수도학회지 / 28권 / 2호 / 151 ~ 160페이지
· 저자명 : 신경숙, 이태우, 차재환, 임윤대, 박승국, 강경석, 송의열

초록

Capacitive deionization(CDI) has many advantages over other desalination technologies due to its low energy consumption, less environmental pollution and relative low fouling potential. The objectives of this study are evaluate the performance of CDI which can be used for dissolved salts removal from sewage. To identify ion selectivity of nitrate and phosphate in multi-ionic solutions and adsorption/desorption performance related to applied potential, a series of laboratory scale experiments were conducted using a CDI unit cell with activated carbon electrodes. The CDI process was able to achieve more than 75 % TDS and NO3-, NH4+ removals, while phosphate removal was 60.8 % and is inversely related in initial TDS and HCO3- concentration. In continuous operation, increasing the inner cell pressure and reduction of TDS removal ability were investigated which are caused by inorganic scaling and biofouling. However a relative mild cleaning solution(5 % of citric acid for calcium scaling and 500 mg/L of NaOCl for organic fouling) restored the electrochemical adsorption capacity of the CDI unit to its initial level.

영어초록

Capacitive deionization(CDI) has many advantages over other desalination technologies due to its low energy consumption, less environmental pollution and relative low fouling potential. The objectives of this study are evaluate the performance of CDI which can be used for dissolved salts removal from sewage. To identify ion selectivity of nitrate and phosphate in multi-ionic solutions and adsorption/desorption performance related to applied potential, a series of laboratory scale experiments were conducted using a CDI unit cell with activated carbon electrodes. The CDI process was able to achieve more than 75 % TDS and NO3-, NH4+ removals, while phosphate removal was 60.8 % and is inversely related in initial TDS and HCO3- concentration. In continuous operation, increasing the inner cell pressure and reduction of TDS removal ability were investigated which are caused by inorganic scaling and biofouling. However a relative mild cleaning solution(5 % of citric acid for calcium scaling and 500 mg/L of NaOCl for organic fouling) restored the electrochemical adsorption capacity of the CDI unit to its initial level.

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