TiO2 코팅 고정화 기술의 장기 공용성 시험에 따른 NOx 제거효율 평가

서지정보

· 발행기관 : 한국도로학회
· 수록지 정보 : 한국도로학회논문집 / 25권 / 5호
· 저자명 : 김광현, 안희락, 이승우, 김영규

목차

1. 서론
2. TiO2 콘크리트 개요
2.1. 광촉매 소재 TiO2의 특성
2.2. 이론적 배경 및 국내 ・ 외 TiO2 적용 콘크리트 사례
3. TiO2 코팅 콘크리트의 장기 공용성 검토
3.1. 실험 전략 및 소재 선정
3.2. TiO2 코팅용액 최적 혼합비율 선정
3.3. TiO2 코팅 콘크리트 시편제작
4. TiO2 콘크리트의 장기 공용성 평가
4.1 실험 전략
4.2. TiO2 콘크리트 동결융해 저항성 시험 개요
4.3. TiO2 콘크리트 표면박리 저항성 시험 개요
4.4. TiO2 콘크리트 NOx 제거효율 평가 개요
5. TiO2 코팅 콘크리트의 장기 공용성 평가
5.1. 표면박리 저항성 시험에 따른 NOx 제거효율 평가
5.2. 동결융해 저항성 시험에 따른 NOx 제거효율 평가
6. 결론
감사의 글

영어초록

PURPOSES : The increase in particulate matter due to increased air pollutant emissions has become a significant social issue. According to the Ministry of Environment, air pollutants emitted from large-scale businesses in 2022 increased by 12.2% compared to the previous year, indicating that air pollution is accelerating owing to excessive industrialization. In this study, TiO2, which is used to reduce airborne particulate, was used. The TiO2 coating fixation and dynamic pressure coating-type TiO2 fixation methods were used to solve the material peeling phenomenon caused by gravity, which is a limitation when the TiO2 penetration method is applied to a vertical concrete structure along the road. The long-term durability and performance were analyzed through environmental resistance and NOx removal efficiency evaluation experiments. These analyses were then assessed by comparing the NOx removal efficiency with the dynamic pressure permeationtype TiO2 fixation method used in previous studies. METHODS : To evaluate the long-term durability and performance of the TiO2 coating fixation method and dynamic pressure coating TiO2 fixation method for vertical concrete structures, specimens were manufactured based on roadside vertical concrete structures. Environmental resistance tests such as the surface peeling resistance test (ASTM C 672) and freeze-thaw resistance test (KS F 2456) were conducted to evaluate the long-term durability. To evaluate the long-term performance, the NOx removal efficiency of TiO2 concrete owing to road surface deterioration during the environmental resistance test was evaluated using the NOx removal efficiency evaluation equipment based on the ISO 22197-1 standard. This evaluation was compared and analyzed using the dynamic pressure infiltration TiO2 fixation method. RESULTS : The long-term durability of the TiO2 coating fixation and dynamic pressure coating TiO2 fixation methods were evaluated using environmental resistance tests. During the surface peeling resistance test, the TiO2 material degraded and partially detached from the concrete. However, the NOx removal efficiency was ensured by the non-deteriorated and fixed TiO2 material. The long-term performance was confirmed through a freeze-thaw resistance test to evaluate the NOx removal efficiency after 300 cycles of surface deterioration. The results showed that when the TiO2 coating fixation and dynamic pressure infiltration TiO2 fixation methods were applied to vertical concrete structures, the durability of the structure was not compromised. In comparison to the dynamic pressure infiltration TiO2 fixation method, the NOx removal efficiency observed during the surface peeling resistance test was lower, while the freeze-thaw test exhibited notably higher removal efficiency. CONCLUSIONS : To solve the material peeling phenomenon caused by gravity, the long-term durability and performance were evaluated by applying the TiO2 coating fixation and dynamic pressurized coating TiO2 fixation methods to vertical concrete specimens. Long-term durability was confirmed through environmental resistance tests, and long-term utility was secured by measuring the NOx removal efficiency according to surface degradation. These findings show that implementing the TiO2 coating fixation method and dynamic pressure coating TiO2 fixation methods on-site effectively reduce NOx.

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