BaF2 침전 및 불화물 용융염 전해 제련을 통한 폐 산세액 내 지르코늄 회수

서지정보

· 발행기관 : 한국재료학회
· 수록지 정보 : 한국재료학회지 / 26권 / 12호
· 저자명 : 한슬기, Hayk H. Nersisyan, 이영준, 최정훈, 이종현

영어초록

Zirconium(Zr) nuclear fuel cladding tubes are made using a three-time pilgering and annealing process. In order to remove the oxidized layer and impurities on the surface of the tube, a pickling process is required. Zr is dissolved in HF and HNO3 mixed acid during the process and pickling waste acid, including dissolved Zr, is totally discarded after being neutralized. In this study, the waste acid was recycled by adding BaF2, which reacted with the Zr ion involved in the waste acid; Ba2ZrF8 was subsequently precipitated due to its low solubility in water. It is very difficult to extract zirconium from the as-recovered Ba2ZrF8 because its melting temperature is 1031 oC. Hence, we tried to recover Zr using an electrowinning process with a low temperature molten salt compound that was fabricated by adding ZrF4 to Ba2ZrF8 to decrease the melting point. Change of the Zr redox potential was observed using cyclic voltammetry; the voltage change of the cell was observed by polarization and chronopotentiometry. The structure of the electrodeposited Zr was analyzed and the electrodeposition characteristics were also evaluated.

참고자료

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