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Styrene Divinylbenzene Copolymer 예비레포트

"Styrene Divinylbenzene Copolymer 예비레포트"에 대한 내용입니다.
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최초등록일 2024.09.27 최종저작일 2024.09
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Styrene Divinylbenzene Copolymer 예비레포트
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    목차

    1. 이론적 배경
    1.1 Styrene Divinylbenzene Copolymer
    1.2 현탁중합 (Suspension Polymerization)

    2. 실험 준비물

    3. 시약 조사
    3.1 benzene
    3.2 Styrene
    3.3 Divinylbenzene
    3.4 benzoyl peroxide

    4. 실험 방법

    5. 결과예상 및 기기분석
    5.1 IR
    5.2 TGA
    5.3 DSC

    6. 참고 문헌

    본문내용

    1. 이론적 배경

    1.1 Styrene Divinylbenzene Copolymer

    스티렌은 단일중합체를 만드는 데도 많이 사용되지만 다른 공단량체와 함께 공중합체를 만드는 데도 널리 이용되고 있다. 공단량체에는 부타디엔, 아크릴로니트릴, 메텔메타크릴레이트 등이 있으며 이로부터 얻어지는 공중합체는 SBR, SAN, SM 등이 있다.

    스티렌과 디비닐벤젠의 공중합체를 제조하는 경우 디비닐벤젠이 두 개의 이중결합을 가지므로 가교 결합이 일어나 열가소성과 용매에 대한 용해성이 감소한다. 그러나 이러한 가교 공중합체는 특별한 용도로 사용되며 가장 중요한 응용은 이온 교환수지이다. 이들 공중합체는 주로 10~50 메쉬의 비드(bead) 형태로 보통 현탁중합에 의해 제조된다. 이러한 가교 공중합체는 여러 종류의 화학약품에 안정하며, 팽윤성이 작고 충분한 기계적 강도를 가지고 있다. 이렇게 3차원적 가교구조를 가지는 불용성 고분자에 -SO3H나 -COOH와 같은 산성기나 N+R3OH와 같은 염기성기 등을 부여하면 이온을 교환할 수 있는 능력을 가지게 되며 치환기의 종류에 따라 양이온 교환수지와 음이온 교환수지로 나눌 수 있다. 가교도는 사용된 디비닐벤젠의 양에 따라 결정되는데 보통 8%정도의 표준가교도를 중심으로 저ㆍ고 가교도로 분류한다. 가교도는 수지의 성능에 크게 영향을 주며 가교도가 커지면 세공의 크기가 감소하므로 함수도, 팽윤도가 감소하면 반대로 밀도는 커진다. 따라서 단위부피당의 이온 교환용량이나 선택 계수가 증가하여 이온교환속도, 재생효율, 큰 분자 이온의 교환능력이 저하되며 유기물에 대한 오염성이 커진다. 그림1은 디비닐벤젠 함량에 따른 스티렌과 디비닐벤젠 가교공중합체의 톨루엔에 대한 팽윤도를 보여준다.

    참고자료

    · 이론적 배경, 실험준비물, 실험방법 : 한국고분자학회, 『고분자실험』, 자유아카데미, 1993, p84~86
    · 현탁중합 : 한국고분자학회, 『고분자실험』, 자유아카데미, 1993, p59
    · benzoyl peroxide의 개시반응 : http://www.chemistryculture.org
    · 시약조사 : wikipedia
    · 그림 . poly(styrene-co-divinylbenzene) : wikipedia
  • AI와 토픽 톺아보기

    • 1. Styrene Divinylbenzene Copolymer
      Styrene divinylbenzene copolymer is an important material in various industrial applications due to its unique properties. It is a cross-linked polymer formed by the copolymerization of styrene and divinylbenzene monomers. The incorporation of divinylbenzene, a multifunctional monomer, results in a highly cross-linked and rigid structure, which provides the copolymer with excellent thermal and chemical stability, as well as high mechanical strength. This makes it suitable for applications such as ion-exchange resins, adsorbents, and chromatographic media. The degree of cross-linking can be controlled by adjusting the ratio of styrene to divinylbenzene, allowing for the tailoring of the copolymer's properties to meet specific requirements. Overall, styrene divinylbenzene copolymer is a versatile and widely used material in the chemical and materials science industries.
    • 2. 현탁중합
      현탁중합은 고분자 합성에 널리 사용되는 중요한 중합 기술 중 하나입니다. 이 방법은 불용성 단량체를 물과 같은 분산매 내에서 작은 액적 형태로 유지하면서 중합을 진행하는 것이 특징입니다. 이를 통해 균일한 입자 크기와 형태를 가진 고분자 입자를 얻을 수 있습니다. 또한 반응 열 제어, 연속 공정 적용, 저점도 등의 장점으로 인해 다양한 고분자 제품 생산에 활용됩니다. 특히 페인트, 코팅, 접착제 등의 분산액 제조에 널리 사용되고 있습니다. 현탁중합은 고분자 산업에서 매우 중요한 역할을 하며, 지속적인 연구를 통해 공정 효율성 및 제품 품질 향상이 이루어지고 있습니다.
    • 3. Benzene
      Benzene is a widely used and important aromatic hydrocarbon compound with a unique cyclic structure. It is a key building block in the petrochemical industry and serves as a precursor for the synthesis of a wide range of other organic compounds. Benzene's high reactivity and versatility make it a valuable raw material for the production of plastics, resins, dyes, detergents, and pharmaceuticals. However, benzene is also known to be a carcinogenic substance, and its exposure can pose significant health risks. Therefore, strict regulations and safety measures are in place to control its production, handling, and use. Ongoing research aims to develop alternative processes and materials to reduce the reliance on benzene while maintaining its essential role in the chemical industry. Overall, benzene remains a critical component in modern chemistry and industry, but its potential hazards require careful management and the exploration of safer alternatives.
    • 4. Styrene
      Styrene is a versatile and widely used aromatic monomer that plays a crucial role in the production of various polymeric materials. Its ability to undergo polymerization, both through addition and condensation reactions, makes it a valuable building block for a wide range of applications. Styrene-based polymers, such as polystyrene, acrylonitrile-butadiene-styrene (ABS), and styrene-butadiene rubber (SBR), are extensively used in the manufacturing of consumer goods, construction materials, automotive parts, and many other products. The unique properties of styrene, including its transparency, rigidity, and thermal insulation, contribute to its widespread use. However, concerns have been raised about the potential health and environmental impacts of styrene, particularly regarding its potential carcinogenicity. Ongoing research and development efforts aim to address these concerns by exploring alternative monomers, improving production processes, and developing safer handling and disposal methods. Overall, styrene remains an essential component in the modern chemical industry, but its responsible and sustainable use is crucial.
    • 5. Divinylbenzene
      Divinylbenzene (DVB) is a multifunctional aromatic monomer that plays a crucial role in the synthesis of cross-linked polymeric materials. Its ability to undergo two simultaneous vinyl polymerization reactions allows it to create highly cross-linked and rigid polymer structures. This property makes DVB an essential component in the production of ion-exchange resins, adsorbents, and chromatographic media, where the cross-linked structure provides enhanced mechanical and thermal stability, as well as specific adsorption and separation capabilities. Additionally, DVB is used as a cross-linking agent in the synthesis of various other polymers, such as styrene-divinylbenzene copolymers, which exhibit exceptional chemical and thermal resistance. The degree of cross-linking can be tailored by adjusting the DVB content, enabling the fine-tuning of the polymer's properties to meet specific application requirements. While the use of DVB is essential in many industrial processes, its potential environmental and health impacts, particularly regarding its potential carcinogenicity, require careful consideration and the development of safer alternatives or production methods.
    • 6. Benzoyl peroxide
      Benzoyl peroxide is a widely used organic peroxide compound that plays a significant role in various chemical and industrial applications. Its primary function is as an initiator or catalyst in free-radical polymerization reactions, making it an essential component in the production of many polymeric materials, such as acrylic resins, polyester resins, and rubber compounds. Benzoyl peroxide's ability to generate free radicals under thermal or UV-light activation allows for the controlled initiation and propagation of polymerization reactions, enabling the synthesis of a wide range of polymers with tailored properties. Additionally, benzoyl peroxide is used as a bleaching agent, disinfectant, and acne treatment due to its oxidizing properties. However, the use of benzoyl peroxide is not without concerns, as it can be potentially hazardous and requires careful handling and storage. Ongoing research aims to develop safer alternative initiators and explore more environmentally friendly production and disposal methods to mitigate the risks associated with benzoyl peroxide while maintaining its valuable applications in the chemical industry.
    • 7. IR 분석
      IR (Infrared) analysis is a powerful analytical technique that plays a crucial role in the characterization and identification of various materials, including polymers, organic compounds, and inorganic substances. By measuring the absorption or transmission of infrared radiation by a sample, IR analysis provides valuable information about the molecular structure, functional groups, and chemical composition of the material. This technique is widely used in research, quality control, and process monitoring across a range of industries, such as chemistry, materials science, and pharmaceuticals. The ability to obtain detailed structural information without the need for complex sample preparation makes IR analysis a versatile and efficient tool for both qualitative and quantitative analysis. Ongoing advancements in IR instrumentation, data analysis software, and the development of specialized sampling techniques have further expanded the applications of IR analysis, enabling researchers and industry professionals to gain deeper insights into the properties and behavior of complex materials. As a complementary technique to other analytical methods, IR analysis remains an indispensable tool in the arsenal of modern analytical chemistry.
    • 8. TGA 분석
      Thermogravimetric Analysis (TGA) is a widely used analytical technique that provides valuable information about the thermal stability and decomposition behavior of various materials, including polymers, ceramics, and inorganic compounds. By continuously measuring the change in the mass of a sample as a function of temperature or time, TGA allows researchers and analysts to gain insights into the thermal properties, composition, and degradation mechanisms of the material under investigation. This technique is particularly useful in the characterization of polymers, where it can be used to determine the thermal stability, identify the presence of additives or impurities, and study the kinetics of thermal decomposition. TGA data can also be used to calculate important parameters such as the onset of degradation, the temperature of maximum weight loss, and the residual mass at high temperatures. The versatility of TGA, combined with its ability to provide quantitative and reproducible data, makes it an indispensable tool in materials science, polymer engineering, and a wide range of other applications where the thermal behavior of materials is of critical importance. Ongoing advancements in TGA instrumentation and data analysis software continue to expand the capabilities and applications of this essential analytical technique.
    • 9. DSC 분석
      Differential Scanning Calorimetry (DSC) is a powerful analytical technique that is widely used to study the thermal behavior and phase transitions of a wide range of materials, including polymers, metals, ceramics, and biological samples. By measuring the difference in heat flow between a sample and a reference material as a function of temperature or time, DSC provides valuable information about the thermal events occurring within the sample, such as melting, crystallization, glass transitions, and chemical reactions. This technique is particularly useful in the characterization of polymers, where it can be used to determine the glass transition temperature, melting point, and degree of crystallinity, all of which are crucial parameters in understanding the material's properties and performance. DSC data can also be used to study the effects of additives, fillers, and other components on the thermal behavior of polymers, as well as to investigate the kinetics of thermal transitions. The versatility and sensitivity of DSC, combined with its ability to provide quantitative and reproducible data, make it an indispensable tool in materials science, polymer engineering, and a wide range of other applications where the thermal properties of materials are of critical importance. Ongoing advancements in DSC instrumentation and data analysis software continue to expand the capabilities and applications of this essential analytical technique.
    • 10. Styrene Divinylbenzene Copolymer
      Styrene divinylbenzene copolymer is an important and versatile material that has found widespread applications in various industries. The copolymerization of styrene and divinylbenzene monomers results in a highly cross-linked and rigid polymer structure, which provides exceptional thermal and chemical stability, as well as high mechanical strength. These properties make styrene divinylbenzene copolymers suitable for a wide range of applications, including ion-exchange resins, adsorbents, and chromatographic media. The degree of cross-linking can be tailored by adjusting the ratio of styrene to divinylbenzene, allowing for the optimization of the copolymer's properties to meet specific requirements. However, the use of styrene and divinylbenzene, which are derived from petrochemical sources, raises concerns about the environmental impact and sustainability of these materials. Ongoing research efforts are focused on exploring alternative monomers, developing more environmentally friendly production processes, and finding ways to recycle and reuse styrene divinylbenzene copolymers. Overall, this material remains a crucial component in various industries, and the continued advancement of its synthesis and applications is essential for meeting the growing demand for high-performance and sustainable polymeric materials.
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