서울대학교 유기무기실험 무기 part 1,2주차 보고서 ferrocene과 그 derivative 합성

목차

1. Abstract
2. Introduction
3. Materials and Methods
4. Experimental Procedure
5. Results
6. Discussion
7. Conclusion
8. References

본문내용

Abstract
Ferrocene and its derivatives were synthesized and analyzed using various techniques. Ferrocene was synthesized from cyclopentadiene and Fe(II) salt. Acetylferrocene and 1-hydroxyethylferrocene were synthesized via a Friedel-Crafts acylation and reduction, respectively. X-ray crystallography showed that ferrocene usually has a staggered arrangement. Cyclic voltammetry demonstrated that the oxidation of ferrocene becomes more difficult with increasing acetylation.

Introduction
Organometallic compounds are characterized by the presence of covalent bonds between carbon and metal atoms. These compounds are synthesized by combining various organic ligands with metal centers. Some organometallic compounds play a crucial role in oxidation-reduction and acid-base reactions, and their catalytic properties often depend on the oxidation state of the metal. One notable example is ferrocene ((η5−C5H5)2Fe), an organometallic compound where a central iron (Fe) atom is sandwiched between two cyclopentadienyl anions.

참고자료

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· Elgrish, N.; Rountree, K. J.; McCarthy, B. D.; Rountree, E. S.; Eisenhart, T. T.; Dempsey, J. L. A Practical Biginner’s Guide to Cyclic Voltammetry. Journal of Chemical Education 2017, 95 (2), 197.
· Friedel, C.; Crafts, J. M. Sur une nouvelle méthode générale de synthèse d'hydrocarbures, d'acétone, etc... Compt. Rend 1877, 84.
· Lau W. S. Infrared characterization for microelectronics; World Scientific, 1999.