Surface oxidation of PAN‑based ultrahigh modulus carbon fibers (UHMCFs) and its effect on the properties of UHMCF/EP composites

서지정보

ㆍ발행기관 : 한국탄소학회 ㆍ수록지정보 : Carbon letters
ㆍ저자명 : Xinyu Wang, Xin Qian, Yonggang Zhang, Xuefei Wang, Shulin Song, Cheng Zhang

목차

Abstract
1 Introduction
2 Experimental
2.1 Materials
2.2 HNO3 oxidation of UHMCFs
2.3 Characterization
3 Results and discussion
3.1 Surface morphology analysis by SEM
3.2 XRD analysis
3.3 Raman spectroscopy analysis
3.4 Surface chemistry by XPS
3.5 Surface wettability analysis and interfacial shear strength
3.6 Mechanical properties of UHMCFs and UHMCFEP composites
3.7 Effect of HNO3 oxidation on the mechanical properties of UHMCFs
4 Conclusions
Acknowledgements
References

영어 초록

In this study, nitric acid oxidation with varied treatment temperature and time was conducted on the surfaces of polyacrylonitrile- based ultrahigh modulus carbon fibers. Scanning electron microscopy, X-ray photoelectron spectroscopy, Raman spectroscopy and surface tension/dynamic contact angle instruments were used to investigate changes in surface topography and chemical functionality before and after surface treatment. Results showed that the nitric acid oxidation of ultrahigh modulus carbon fibers resulted in decreases in the values of the crystallite thickness Lc and graphitization degree. Meanwhile, increased treating temperature and time made the decreases more obviously. The surfaces of ultrahigh modulus carbon fibers became much more activity and functionality after surface oxidation, e.g., the total surface energy of oxidized samples at 80 °C for 1 h increased by 27.7% compared with untreated fibers. Effects of surface nitric acid oxidation on the mechanical properties of ultrahigh modulus carbon fibers and its reinforced epoxy composites were also researched. Significant decreases happened to the tensile modulus of fibers due to decreased Lc value after the nitric acid oxidation. However, surface treatment had little effect on the tensile strength even as the treating temperature and processing time increased. The highest interfacial shear strength of ultrahigh modulus carbon fibers/epoxy composites increased by 25.7% after the nitric acid oxidation. In the final, surface oxidative mechanism of ultrahigh modulus carbon fibers in the nitric acid oxidation was studied. Different trends of the tensile strength and tensile modulus of fibers in the nitric acid oxidation resulted from the typical skin–core structure.

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