Preparation of graphene‑coated anodic alumina substrates for selective molecular transport

서지정보

ㆍ발행기관 : 한국탄소학회 ㆍ수록지정보 : Carbon letters / 30권 / 1호
ㆍ저자명 : Sultan Akhtar, Sadaqat Ali, Feras M. Kafiah, Ahmed Ibrahim, Asif Matin, Tahar Laoui

목차

Abstract
Graphic abstract
1 Introduction
2 Materials and methods
2.1 Materials
2.2 Production, transfer, and characterization of graphene
2.3 Molecular transport experiments
2.4 Interfacial polymerization (IP)
3 Results and discussion
3.1 Optical microscopy analysis of uncoated membranes
3.2 SEM analysis of uncoated membranes
3.3 AFM analysis of uncoated membranes
3.4 TEM, AFM, and Raman spectroscopy analyses of graphene
3.5 SEM and AFM analyses of graphene-coated membranes
3.6 Molecular transport analysis of bare and coated substrates
4 Conclusion
Acknowledgements
References

영어 초록

In this paper, we report graphene composite membranes prepared by transfer of a layer of chemical vapor deposition graphene onto porous anodic alumina (AA) substrates with nominal pore size 20 and 30 nm, referred as 20AA and 30AA. The coated and uncoated substrates were characterized using optical and electron microscopy techniques. The bare substrates exhibited a smooth surfaces with a well-organized array of hexagonal pores, displaying an average pore size of 17 ± 3 (20AA) and 23 ± 3 nm (30AA). The scanning electron microscopy and atomic force microscopy analyses confirmed the successful transfer of graphene layer onto the target substrates. The molecular transport study was performed by introducing 0.5 M potassium chloride (KCl) and deionized water in a Side-bi-Side Franz diffusion cell. The graphene/20AA specimen blocked 66% ions transport, and graphene/30AA membrane about 64%. The ions blockage exceeded 90%, near the characteristics of defectfree graphene when the defects of the transferred graphene were sealed with Nylon 6,6. The results of this study suggest the potential use of graphene on AA substrates for water desalination and gas purification applications.

참고 자료

없음