Preparation of ethanediamine‑doped carbon quantum dots and their applications in white LEDs and fluorescent TLC plate

서지정보

ㆍ발행기관 : 한국탄소학회 ㆍ수록지정보 : Carbon letters / 32권 / 2호
ㆍ저자명 : Wenya Wang, Chunru Zhou, Weina Song, Liguo Wei, Peng Wu

목차

Abstract
1 Introduction
2 Materials and methods
2.1 Materials
2.2 Synthesis of N-CQDs
2.3 Preparation of white LEDs
2.4 Application of fluorescent TLC
2.5 Characterization and quantum yields test
3 Results and discussion
3.1 Selection of nitrogen source
3.2 Morphology of the N-CQDs
3.3 Surface properties of N-CQDs
3.4 Optical properties of N-CQDs
3.5 The application of N-CQDs3 on the color of LEDs lighting
3.6 Application of N-CQDs3 in TLC plate
4 Conclusions
Acknowledgements
References

영어 초록

Herein, a facile bottom–up approach for producing nitrogen-doped carbon quantum dots (N-CQDs) was carried out by the hydrothermal treatment of microcrystalline cellulose, in the presence of different nitrogen sources (blank/urea/ammonia water/ethanediamine(EDA)/Hexamethylenetetramine). The result showed that the fluorescence intensity and quantum yields (QYs) of N-CQDs with different nitrogen sources are all higher than that without nitrogen source. Compared with the other three nitrogen sources, N-CQDs prepared by EDA not only have the highest fluorescence intensity but also the largest QYs of 51.39%. Therefore, EDA was chosen as the nitrogen source to prepare N-CQDs. The obtained N-CQDs are uniform spherical particles with a diameter of 2.76 nm. The N-CQDs also exhibit excitation-dependent and long-wave emission properties. The emission range of N-CQDs is 470–540 nm. Moreover, N-CQDs as fluorescent agents successfully acted on purple LEDs (λem = 365 nm) to achieve white LEDs light emission. At the same time, a fluorescent thin layer chromatography plate was successfully prepared using N-CQDs, silica gel G and Sodium carboxymethylcellulose as raw materials. The separation trajectory of mixed sample of Sudan red III and kerosene on the fluorescent TLC plate is obviously clearer than that of the TLC plate.

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