코로나 방전 저온 플라즈마를 이용한 황화수소 제거에서 습도 및 인가전력의 영향
(주)코리아스칼라
- 최초 등록일
- 2017.01.04
- 최종 저작일
- 2016.09
- 8페이지/ 어도비 PDF
- 가격 4,000원
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서지정보
ㆍ발행기관 : 한국냄새환경학회
ㆍ수록지정보 : 실내환경 및 냄새 학회지 / 15권 / 3호
ㆍ저자명 : 강정희, 조준표, 남윤기, 송지현
목차
1. 서 론
2. 실험재료 및 방법
2.1 Lab-scale 코로나 플라즈마 장치 및 실험 조건
2.2 Pilot-scale 코로나 플라즈마 장치 및 실험 조건
2.3 측정방법
3. 결과 및 고찰
3.1 Lab-scale 플라즈마에서의 황화수소 산화특성
3.2 Lab-scale 플라즈마의 운전특성
3.3 Pilot-scale 플라즈마의 황화수소 제거
4. 결 론
References
영어 초록
Hydrogen sulfide (H2S) emitted from various sources is a major odorous compound, and non-thermal plasma (NP) has emerged as a promising technique to eliminate H2S. This study was conducted to investigate lab-scale and pilot-scale NP reactors using corona discharge for the removal of H2S, and the effects of relative humidity, applied electrical power on reactor performance and ozone generation were determined. A gas stream containing H2S was injected to the lab-scale NP reactor, and the changes in H2S and ozone concentration were monitored. In the pilotscale NP experiment, the inlet concentration and flow rate were modified to determine the effect of relative humidity and applied power on the NP performance. In the lab-scale NP experiments, H2S removal was found to be the 1st-order reaction in the presence of ozone. On the other hand, when plasma reaction and ozone generation were initiated after H2S was introduced, the H2S oxidation followed the 0th-order kinetics. The ratio of indirect oxidation by ozone to the overall H2S removal was evaluated using two different experimental findings, indicating that approximately 70% of the overall H2S elimination was accounted for by the indirect oxidation. The pilotscale NP experiments showed that H2S introduced to the reactor was completely removed at low flow rates, and approximately 90% of H2S was eliminated at the gas flow rate of 15 m3/min. Furthermore, the elimination capacity of the pilot-scale NP was 3.4 g/m3·min for the removal of H2S at various inlet concentrations. Finally, the experimental results obtained from both the lab-scale and the pilot-scale reactor operations indicated that the H2S mass removal was proportional to the applied electrical power, and average H2S masses removed per unit electrical power were calculated to be 358 and 348 mg-H2S/kW in the lab-scale and the pilot-scale reactors, respectively. To optimize energy efficiency and prevent the generation of excessive ozone, an appropriate operating time of the NP reactor must be determined.
참고 자료
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