Synthesis of Zr0.73Y0.27O1.87 Crystals by the Bridgman-Stockbager Method
(주)코리아스칼라
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- 2016.04.02
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- 2002.01
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서지정보
ㆍ발행기관 : 한국지구과학회
ㆍ수록지정보 : 한국지구과학회지 / 23권 / 1호
ㆍ저자명 : Kim, Won-Sa, Yu, Young-Moon, Lee, Jin-Ho
영어 초록
A colorless and transparent zirconium oxide (Zr0.73Y0.27O1.87) crystal has been synthesized by the Bridgman-Stockbager method. The gem-quality material is produced by adding 20∼25 wt.% Y2O3 (stabilizer) and 0.04 wt.% Nd2O3 (decolorising agent) to the ZrO2 powder. It shows a vitreous luster with a slight oily appearance. Under a polarizing microscope, it shows isotropic nature with no appreciable anisotropism. Mohs hardness value and specific gravity is measured to be 8∼8½ and 5.85, respectively. Under ultraviolet light it shows a faint white glow. The crystal structure of yttria-stabilized zirconia with 0.27 at.% Y has been re-investigated, using single crystal X-ray diffraction, and confirmed to be a cubic symmetry, space group Fmøverline3m (O5h) with a=5.1552(5) A, V=136.99(5) A3, Z=4. The stabilizer atoms randomly occupy the zirconium sites and there are displacements of oxygen atoms with amplitudes of δ/a∼0.033 and 0.11 along 〈110〉 and 〈111〉 from the ideal positions of the fluorite structure, respectively.
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